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Peptide chemistry is unforgiving

Studies show it may be true - temporarily

Signal Peptide In molecular biology, a short amino acid sequence that directs a protein to a specific cellular location

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The application of exogenous melatonin prompted the endogenous melatonin biosynthetic process through antagonistic interaction with calcium, thereby safeguarding the product against chilling injury and postharvest deterioration, as indicated in Figure 5B